Document Type
Article
Publication Date
2-3-2021
Publication Title
RSC Advances
Volume
11
Issue
11
First page number:
6353
Last page number:
6360
Abstract
© The Royal Society of Chemistry 2021. The (NH4)2[ReF6] (1) salt was studied by X-ray diffraction, Raman spectroscopy, theoretical calculations, and magnetic measurements.1crystallizes in the trigonal space groupP3̄m1 (Re-F = 1.958(5) Å). In the Raman spectrum of1, splitting of the observed peaks was observed and correlated to the valence frequencies of vibration of the [ReF6]2−anion. The study of the magnetic properties of1, through DC and AC magnetic susceptibility measurements, reveals the coexistence of metamagnetism and slow relaxation of magnetization at low temperature, which is unusual in the molecular systems based on the paramagnetic 5d metal ions reported so far.
Disciplines
Chemistry | Physical Chemistry
File Format
File Size
936 KB
Language
English
Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.
Repository Citation
Louis-Jean, J.,
Balasekaran, S.,
Lawler, K.,
Sanchis-Perucho, A.,
Martínez-Lillo, J.,
Smith, D.,
Forster, P.,
Salamat, A.,
Poineau, F.
(2021).
Coexistence of Metamagnetism and Slow Relaxation of Magnetization in Ammonium Hexafluoridorhenate.
RSC Advances, 11(11),
6353-6360.
http://dx.doi.org/10.1039/d0ra10325j