Near-Edge X-ray Absorption Fine Structure Study of Disordering in Gd2(Ti1-yZry)2O7 Pyrochlores
Disorder in Gd2(Ti1-yZry)2O7 pyrochlores, for y = 0.0-1.0, is investigated by Ti 2p and O 1s near-edge X-ray absorption fine structure spectroscopy. Ti4+ ions are found to occupy octahedral sites in Gd2Ti2O7 with a tetragonal distortion induced by vacant oxygen sites. As Zr substitutes for Ti, the tetragonal distortion decreases, and Zr coordination increases from 6 to 8. The migration of oxygen ions from 48f or 8b sites to vacant 8a sites compensate for the increased Zr coordination, thereby reducing the number of vacant 8a sites, which further reduces the tetragonal distortion and introduces more disorder around Ti. This is evidence for simultaneous cation disorder with anion migration.
Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Elementary Particles and Fields and String Theory | Physical Chemistry
Use Find in Your Library, contact the author, or use interlibrary loan to garner a copy of the article. Publisher copyright policy allows author to archive post-print (author’s final manuscript). When post-print is available or publisher policy changes, the article will be deposited
Adams, E. M.,
Weber, W. J.,
Begg, B. D.,
Mun, B. S.,
Shuh, D. K.,
Lindle, D. W.,
Gullikson, E. M.,
Perera, R. C.
Near-Edge X-ray Absorption Fine Structure Study of Disordering in Gd2(Ti1-yZry)2O7 Pyrochlores.
Journal of Physical Chemistry B, 109(4),