Document Type
Article
Publication Date
2010
Publication Title
Journal of Chemical Physics
Volume
133
Issue
014306
First page number:
014306-1
Last page number:
014306-6
Abstract
We have investigated the photofragmentation properties of the three-membered ring heterocyclic molecule ethylene sulfide or thiirane, C2H4S, by time-of-flight mass spectroscopy. Positive ions have been collected as a function of photon energy around the S K ionization threshold. Branching ratios were derived for all detected ions, which are informative of the decay dynamics and photofragmentation patterns of the core-excited species. We present a new assignment of the spectral features around the S K-edge.
Keywords
Atomic orbitals; Electron configuration; Mass spectroscopy; Organosulfur compounds
Disciplines
Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Physical Chemistry
Language
English
Permissions
Copyright American Institute of Physics, used with permission
Publisher Citation
Stolte, Wayne C., and G. Öhrwall. "Sulfur K-edge photofragmentation of ethylene sulfide." The Journal of chemical physics 133 (2010): 014306.
Repository Citation
Stolte, W. C.,
Ohrwall, G.
(2010).
Sulfur K-edge photo-fragmentation of Ethylene Sulfide.
Journal of Chemical Physics, 133(014306),
014306-1-014306-6.
https://digitalscholarship.unlv.edu/chem_fac_articles/7
Included in
Analytical Chemistry Commons, Atomic, Molecular and Optical Physics Commons, Biological and Chemical Physics Commons, Physical Chemistry Commons