Location

University of Nevada, Las Vegas

Start Date

16-4-2011 10:50 AM

End Date

16-4-2011 11:10 AM

Description

Zirconium carbide has been proposed as a coating layer for next generation (“TRISO”) nuclear fuel, and is intended as a diffusion barrier to contain fission products (e.g., Pd). To study the chemical interaction between Pd and ZrC, their interface was investigated using X-ray Photoelectron Spectroscopy (XPS). Pd was step-wise deposited onto ZrC in ultra-high vacuum, and the chemical interaction at the interface was monitored, also as a function of temperature (up to 1000 C). In the presentation, details of the chemical interaction and changes in the chemical environment of Pd and their relevance for TRISO fuel will be discussed.

Keywords

Chemical reactions; Diffusion coatings; Nuclear fuels; Palladium; Zirconium carbide

Disciplines

Atomic, Molecular and Optical Physics | Nuclear | Oil, Gas, and Energy | Physics

Language

English

Comments

Poster co-authors: D. Hanks, S. Krause, T. Hofmann, M. Weir, Y. Zhang, C. Heske, University of Nevada, Las Vegas

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Apr 16th, 10:50 AM Apr 16th, 11:10 AM

Oral presentation: Next generation nuclear fuels

University of Nevada, Las Vegas

Zirconium carbide has been proposed as a coating layer for next generation (“TRISO”) nuclear fuel, and is intended as a diffusion barrier to contain fission products (e.g., Pd). To study the chemical interaction between Pd and ZrC, their interface was investigated using X-ray Photoelectron Spectroscopy (XPS). Pd was step-wise deposited onto ZrC in ultra-high vacuum, and the chemical interaction at the interface was monitored, also as a function of temperature (up to 1000 C). In the presentation, details of the chemical interaction and changes in the chemical environment of Pd and their relevance for TRISO fuel will be discussed.