Document Type

Report

Publication Date

3-2006

First page number:

1

Last page number:

4

Abstract

This research report outlines the current status and progress associated with the electrochemical separation of Curium and Americium. For two and a half years, research has been actively performed on this project, and is currently on schedule for the proposed timelines.

Progress:

• The electrochemical characterization of Ce and Eu complexed with EDTA, NTA, and Citrate has been completed.

• Synthesis of the polymer substrate and the chelating ligand is underway. Approximately 50 grams of disulfide has been produced to produce the chelating thiol group required for the last set of studies.

• Gold substrates have been prepared to perform the 2-D surface chelation using the chelating disulfide and thiol. The goal is to determine the potentials required for chelation.

• Polymer gold composite systems have been prepared and characterized for use with the chelating ligands.

Keywords

Actinide elements; Americium; Cerium; Chelates; Curium; Ligands; Electrochemistry; Europium; Nuclear fuels; Oxidation-reduction reaction; Rare earth metals; Separation (Technology); Thiols

Controlled Subject

Actinide elements; Rare earth metals; Separation (Technology)

Disciplines

Analytical Chemistry | Chemistry | Oil, Gas, and Energy | Physical Chemistry

File Format

pdf

File Size

191 KB

Language

English

Rights

COPYRIGHT UNDETERMINED. For more information about this rights statement, please visit http://rightsstatements.org/vocab/UND/1.0/


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