Fundamental Chemistry of U and Pu in the TBP-Dodecane-Nitric Acid System: Quaterly Report

Authors

Kenneth Czerwinski, University of Nevada, Las VegasFollow
Byron Bennett, University of Nevada, Las Vegas

Document Type

Report

Publication Date

2004

First page number:

1

Last page number:

2

Abstract

The speciation of hexavalent U and tetravalent Pu will be examined in the TBP-dodecane- nitric acid systems. This topic is chosen based on data needs for separation modeling identified by the AFCI. Emphasis will be placed on studying the influence of nitrate and acetohydroxamic acid on U and Pu speciation as well as conditions where a third phase forms in the organic phase. The organic phase will be 30 % TBP in dodecane. Equal volumes of aqueous and organic phase will be used. The speciation of the actinides in the aqueous and organic phase will be determined by a number of different spectroscopic and radiochemical techniques. Additionally the actinide distribution between the phases as a function of conditions will be determined. The project data will be incorporated into models to evaluate separations under a variety of conditions.

Keywords

Nitric acid; Plutonium; Radioactive wastes – Purification; Separation (Technology); Speciation (Chemistry); Tributyl phosphate; Uranium

Controlled Subject

Nitric acid; Radioactive wastes--Purification; Tributyl phosphate

Disciplines

Analytical Chemistry | Chemical Engineering | Chemistry | Oil, Gas, and Energy | Physical Chemistry

File Format

pdf

File Size

151 KB

Language

English

Rights

COPYRIGHT UNDETERMINED. For more information about this rights statement, please visit http://rightsstatements.org/vocab/UND/1.0/

Repository Citation

Czerwinski, K., Bennett, B. (2004). Fundamental Chemistry of U and Pu in the TBP-Dodecane-Nitric Acid System: Quaterly Report. 1-2.
Available at: https://digitalscholarship.unlv.edu/hrc_trp_separations/86