Award Date

5-1-2015

Degree Type

Dissertation

Degree Name

Doctor of Philosophy (PhD)

Department

Mathematical Sciences

First Committee Member

Pengtao Sun

Second Committee Member

Jichun Li

Third Committee Member

Hongtao Yang

Fourth Committee Member

Monika Neda

Fifth Committee Member

Michael Marcozzi

Sixth Committee Member

Hui Zhao

Number of Pages

200

Abstract

Electrohydrodynamics (EHD) is the term used for the hydrodynamics coupled with electrostatics, whose governing equations consist of the electrostatic potential (Poisson) equation, the ionic concentration (Nernst-Planck) equations, and Navier-Stokes equations for an incompressible, viscous dielectric liquid. In this dissertation, we focus on a specic application of EHD - fuel cell dynamics - in the eld of renewable and clean energy, study its traditional model and attempt to develop a new fuel cell model based on the traditional EHD model. Meanwhile, we develop a series of ecient and robust numerical methods for these models, and carry out their numerical analyses on the approximation accuracy. In particular, we analyze the error estimates of nite element method for a simplied 2D isothermal steady state two-phase transport model of Proton Exchange Membrane Fuel Cell (PEMFC) as well as its transient version. On the aspect of hydrodynamics arising in the fuel cell system, the fluid flow through the open channels and porous media at the same time, both Navier-Stokes equations and Darcy's law are involved in the fluid domains, leading to a Navier-Stokes-Darcy coupling problem. In this dissertation, we study a one-continuum model approach, so-called Brinkman model, to overcome this problem in a more ecient way. To develop a new fuel cell model based on EHD theory, in addition to the two-phase transport model of fuel cells, we carry out numerical analyses for Poisson-Nernst-Planck (PNP) equations using both standard FEM and mixed FEM, which are the essential governing equations involved by EHD model. Finally, we are able to further extend the traditional fuel cell model to more general cases in view of EHD characteristics, and develop a new fuel cell model by appropriately combining PNP equations with the traditional fuel cell model. We conduct the error analysis for PNP-Brinkman system in this dissertation.

Keywords

Brinkman; Electrohydrodynamics; Finite element method; Fuel Cell; Navier-Stokes-Darcy coupling; Poisson-Nernst-Planck

Disciplines

Mathematics

Language

English


Included in

Mathematics Commons

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