Document Type

Article

Publication Date

9-2008

Publication Title

Physical Review Letters

Volume

101

Issue

133003

First page number:

4

Abstract

Polarization-dependent resonant inelastic x-ray scattering (RIXS) is shown to be a new probe of molecular-field effects on the electronic structure of isolated molecules. A combined experimental and theoretical analysis explains the linear dichroism observed in Cl 2p RIXS following Cl 1s excitation in HCl and CF3Cl as due to molecular-field effects, including singlet-triplet exchange, indicating polarized-RIXS provides a direct probe of spin-orbit-state populations applicable to any molecule.

Keywords

Atomic orbitals; Chloride compounds; Electron configuration; Linear dichroism

Disciplines

Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Physical Chemistry

Language

English

Permissions

Copyright American Physical Society, used with permission

Identifier

DOI: 10.1103/PhysRevLett.101.133003

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