Title

Elastic peak of K shell excited HCl molecule: comparision HCl-DCl Experiment and theory

Document Type

Article

Publication Date

11-2006

Publication Title

Journal of Electron Spectroscopy and Related Phenomena

Volume

155

First page number:

91

Last page number:

94

Abstract

Femtosecond dynamics has been recently observed by resonant X-ray Raman scattering (RXRS) after excitation along the dissociative Cl 1s → 6ơ* resonance of gas phase HCl. In this paper, we show a method to take into account and correct for self-absorption of the elastic peak, in order to allow for quantitative comparison with theory. We have performed measurements on the DCl molecule exhibiting ultrafast nuclear motion. A comparison between HCl and DCl is presented.

Keywords

Atomic orbitals; DCl; Elastic peak; Electronic excitation; Femtochemistry; HCl; Hydrogen Chloride; Nuclear motion; Raman spectroscopy; RIXS; RXRS; Self-absorption

Disciplines

Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Physical Chemistry

Language

English

Permissions

Use Find in Your Library, contact the author, or use interlibrary loan to garner a copy of the article. Publisher copyright policy allows author to archive post-print (author’s final manuscript). When post-print is available or publisher policy changes, the article will be deposited

Identifier

DOI: 10.1016/j.elspec.2006.11.007

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