Elastic peak of K shell excited HCl molecule: comparision HCl-DCl Experiment and theory
Journal of Electron Spectroscopy and Related Phenomena
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Femtosecond dynamics has been recently observed by resonant X-ray Raman scattering (RXRS) after excitation along the dissociative Cl 1s → 6ơ* resonance of gas phase HCl. In this paper, we show a method to take into account and correct for self-absorption of the elastic peak, in order to allow for quantitative comparison with theory. We have performed measurements on the DCl molecule exhibiting ultrafast nuclear motion. A comparison between HCl and DCl is presented.
Atomic orbitals; DCl; Elastic peak; Electronic excitation; Femtochemistry; HCl; Hydrogen Chloride; Nuclear motion; Raman spectroscopy; RIXS; RXRS; Self-absorption
Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Physical Chemistry
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Stolte, W. C.,
Hudson, A. C.,
Lindle, D. W.
Elastic peak of K shell excited HCl molecule: comparision HCl-DCl Experiment and theory.
Journal of Electron Spectroscopy and Related Phenomena, 155