Title

Tetrafluoridonitridotechnetate(VI) – Reactions and Structures

Document Type

Article

Publication Date

7-25-2018

Publication Title

Journal of Inorganic and General Chemistry

Volume

644

Issue

19

First page number:

1158

Last page number:

1163

Abstract

Dissolution of the polymeric nitridotechnetic(VI) acid in aqueous HF results in the formation of the [TcNF4]– anion. The presence of the paramagnetic anion in such solutions can readily be confirmed by EPR spectroscopy. Addition of CsF or (NEt4)F gives orange‐yellow, diamagnetic solids of the compositions Cs3(NH4)[F4NTc(μ‐O)TcNF4] and (NEt4)3(NH4)[NF2Tc(μ‐O)2TcNF2]2, respectively.

Keywords

Fluorides; Technetium; Nitrido compounds; X-ray structures; EPR

Disciplines

Chemistry

Language

English

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