Photofragmentation of SO2 following Photoexcitation Near the Sulfur L2,3 Threshold
Journal of Electron Spectroscopy and Related Phenomena
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We report an extensive study on total and partial-ion-yield spectroscopy around the S 2p threshold in SO2. All positive and negative single-ion channels have been measured. Several cation fragments with the same mass/charge ratio could be distinguished by taking advantage of the 34S isotope. The O− yield as a function of photon energy shows strong enhancement on the below-threshold resonances with two broad weak peaks above threshold corresponding to doubly excited resonances.
Anions; Atomic orbitals; Core-level; Electron configuration; Fragmentation reactions; Photofragmentation; Sulfur dioxide
Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Physical Chemistry
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Stolte, W. C.,
Tran, I. C.,
Lindle, D. W.
Photofragmentation of SO2 following Photoexcitation Near the Sulfur L2,3 Threshold.
Journal of Electron Spectroscopy and Related Phenomena, 144-147