Preparation and Characterization of Benzotriazolium Perrhenate

Authors

James Louis-Jean, University of Nevada, Las VegasFollow
Harry Jang, University of Nevada, Las Vegas
Keith V. Lawler, University of Nevada, Las VegasFollow
Paul M. Forster, University of Nevada, Las VegasFollow
Jeffrey Ash, University of Nevada, Las Vegas
Frederic Poineau, University of Nevada, Las VegasFollow

Document Type

Article

Publication Date

9-9-2019

Publication Title

Inorganica Chimica Acta

First page number:

1

Last page number:

32

Abstract

The title compound, [C6H6N3][ReO4], crystallizes in the monoclinic space group P21/c (a = 12.854(2) Å; b = 4.9121(8) Å; c = 14.819(2) Å). The solid-state structure of the compound is stabilized by a series of hydrogen bonds. The solubility of [C6H6N3][ReO4] was measured in H2O, CH3OH, and HCl (0.5 M and 6 M). Nuclear magnetic resonance measurements (1H NMR and 13C NMR) were performed, and results were consistent with the presence of the organic cation. The UV-visible spectrum shows a solvent dependency which DFT simulations indicate arise from which benzotriazole species are present in solution.

Keywords

Benzotriazolium; Crystal structure; DFT simulation; NMR spectroscopy; Perrhenate

Disciplines

Inorganic Chemistry

Language

English

Repository Citation

Louis-Jean, J., Jang, H., Lawler, K. V., Forster, P. M., Ash, J., Poineau, F. (2019). Preparation and Characterization of Benzotriazolium Perrhenate. Inorganica Chimica Acta 1-32.
http://dx.doi.org/10.1016/j.ica.2019.119121