Core-level Anionic Photofragmentation of OCS

Document Type

Article

Publication Date

4-2003

Publication Title

Chemical Physics

Volume

289

Issue

1

First page number:

45

Last page number:

49

Abstract

Mass spectroscopy is used to study the formation of the S-, C-, and O- anions after photoexcitation of OCS in the vicinity of the S 2p and C 1s ionization thresholds. Anions are observed both below and above these thresholds. Because anion production is known to be suppressed at core-level shape resonances, the anion measurements serve as a suggestive and complementary tool for identifying above-threshold features in OCS photoabsorption.

Keywords

Anions; Atomic orbitals; Carbonyl sulfide; Electronic excitation; Fragmentation reactions; Mass spectroscopy

Disciplines

Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Physical Chemistry

Language

English

Permissions

Use Find in Your Library, contact the author, or use interlibrary loan to garner a copy of the article. Publisher copyright policy allows author to archive post-print (author’s final manuscript). When post-print is available or publisher policy changes, the article will be deposited

Publisher Citation

Dang, L. T. N., Wayne C. Stolte, G. Öhrwall, M. M. Sant’Anna, I. Dominguez-Lopez, A. S. Schlachter, and Dennis W. Lindle. "Core-level anionic photofragmentation of OCS." Chemical physics 289, no. 1 (2003): 45-49.

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