Document Type

Article

Publication Date

7-1997

Publication Title

Physical Review Letters

Volume

79

Issue

3

First page number:

383

Last page number:

386

Abstract

Experimental and theoretical studies are reported on the inelastic (Raman) scattering of wavelength-selected polarized x rays from the K edge of gas-phase chlorine molecules. The polarized emission spectra exhibit prominent nondipole features consequent of phase variations of the incident and emitted radiation over molecular dimensions, as predicted by the Kramers-Heisenberg scattering formalism. Issues pursuant to the detection of core-hole localization by resonant Raman scattering from homonuclear diatomic molecules are critically examined. [S0031-9007(97)03486-8]

Keywords

Chlorine; Diatomic molecules; Raman effect; Raman spectroscopy

Disciplines

Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Elementary Particles and Fields and String Theory | Physical Chemistry

Language

English

Permissions

Copyright American Physical Society, used with permission

Identifier

DOI: 10.1103/PhysRevLett.79.383

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