Structure and Luminescence Properties of a Nd3+ Doped Bi4Ge3O12 Scintillation Crystal: New Insights from a Comprehensive Study

Authors

Feiyang Chen, Nanyang Normal University
Meng Ju, Nanyang Normal UniversityFollow
Gennday L. Gutsev, Florida A and M UniversityFollow
Xiaoyu Kuang, Sichuan UniversityFollow
Cheng Lu, University of Nevada, Las VegasFollow
Yauyuen Yeung, Hong Kong Institute of EducationFollow

Document Type

Article

Publication Date

1-1-2017

Publication Title

Journal of Materials Chemistry C

Volume

5

Issue

12

First page number:

3079

Last page number:

3087

Abstract

The rare-earth Nd3+ doped bismuth ortho-germanate Bi4Ge3O12 (BGO), serving as an excellent kind of fast scintillator, has been widely used in many scientific and technical areas. However, there are two unsolved problems which hinder its practical applications, namely: (i) there is no detailed information about the microstructure and location sites of Nd3+ ions in the BGO lattice; (ii) it is difficult to determine the electric and magnetic dipole transition mechanisms of Nd3+ doped BGO. Here, the microstructure and site location of Nd3+ ions in BGO have been systematically investigated by means of an unbiased CALYPSO structure search method coupled with first principles calculations. As a result, we have for the first time identified a unique semiconducting phase of the R3 space group where impurity Nd3+ ions occupy exactly the host Bi3+ ion sites with trigonal symmetry. Based on our developed WEPMD method, new sets of free-ion, crystal field and orthogonal correlation crystal field parameters are obtained, yielding a much better agreement between the calculated and observed values for both optical energy levels and Zeeman splitting g-factors of the ground state. Starting from these new set parameters, the majority of electric dipole and magnetic dipole transition lines, including a large number of absorption and emission lines, in the region of visible and near-infrared spectra of Nd3+ ions in BGO are predicted and discussed. It is shown that the main emission channel of Nd3+ doped BGO occurs at the inter-Stark laser transitions of 4F3/2 → 4I11/2 corresponding to an emission wavelength of approximately 1064 nm. © The Royal Society of Chemistry.

Language

english

Repository Citation

Chen, F., Ju, M., Gutsev, G. L., Kuang, X., Lu, C., Yeung, Y. (2017). Structure and Luminescence Properties of a Nd3+ Doped Bi4Ge3O12 Scintillation Crystal: New Insights from a Comprehensive Study. Journal of Materials Chemistry C, 5(12), 3079-3087.
http://dx.doi.org/10.1039/c6tc05657a