Title
Fragmentation of Methyl Chloride Studied by Partial Positive and Negative Ion Yield Spectroscopy
Document Type
Article
Publication Date
2-2007
Publication Title
Journal of chemical physics
Publisher
American Institute of Physics
Volume
126
Issue
8
First page number:
084309-1
Last page number:
084309-8
Abstract
The authors present partial-ion-yield experiments on the methyl chloride molecule excited in the vicinity of the Cl2p and C1s inner shells. A large number of fragments, cations produced by dissociation or recombination processes, as well as anionic species, have been detected. Although the spectra exhibit different intensity distributions depending on the core-excited atom, general observations include strong site-selective fragmentation along the C–Cl bond axis and a strong intensity dependence of transitions involving Rydberg series on fragment size.
Controlled Subject
Chemical bonds; Collisions (Nuclear physics); Ion recombination
Disciplines
Biological and Chemical Physics | Inorganic Chemistry | Nuclear | Physical Chemistry
File Format
File Size
854 KB
Language
English
Permissions
Copyright (2007) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.
Rights
IN COPYRIGHT. For more information about this rights statement, please visit http://rightsstatements.org/vocab/InC/1.0/
Repository Citation
Ceolin, D.,
Piancastelli, M. N.,
Guillemin, R.,
Stolte, W. C.,
Yu, S.,
Hemmers, O.,
Lindle, D. W.
(2007).
Fragmentation of Methyl Chloride Studied by Partial Positive and Negative Ion Yield Spectroscopy.
Journal of chemical physics, 126(8),
084309-1-084309-8.
https://digitalscholarship.unlv.edu/hrc_fac_articles/12
Included in
Biological and Chemical Physics Commons, Inorganic Chemistry Commons, Nuclear Commons, Physical Chemistry Commons