Physical review A
American Physical Society
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Molecular ionization and ionic fragmentation of core excited CO valence and Rydberg states are studied by partial-ion-yield spectroscopy at vibrational resolution. The vibrational intensities of the Rydberg excitations differ significantly depending on the ionization and/or fragmentation channel. The observed intensity variations are explained by nondissociative excited final ionic states of the subsequent molecular Auger decay. The vibrational levels of these final states become selectively depopulated due to interaction with dissociative decay channels leading to ionic fragmentation.
Auger effect; Carbon monoxide; Nuclear excitation; Rydberg states
Atomic, Molecular and Optical Physics | Physical Chemistry
Copyright American Physical Society. Used with permission.
Vibrational-state-dependent decay of the CO C(1s) excitation.
Physical review A, 51(6),