On the Angular Distributions of Molecular Photoelectrons: Dipole Cross Sections for Fixed-in-Space and Randomly Oriented Molecules
Document Type
Article
Publication Date
10-2001
Publication Title
Chemical Physics Letters
Publisher
Elsevier
Volume
346
First page number:
341
Last page number:
346
Abstract
New theoretical expressions are devised employing a dynamical perspective for photoionization cross-sections differential in electron ejection angles for both fixed-in-space and randomly oriented molecules, and comparisons made with K-shell ionization measurements in molecular nitrogen. Closed-form cross-sectional expressions are obtained in the dipole limit in terms of molecular body-frame transition moments and related normalized angular-distribution amplitudes which can be calculated employing interaction-prepared states without reference to specific scattering boundary conditions, and which reduce to more familiar atomic expressions in appropriate limits.
Controlled Subject
Angular distribution (Nuclear physics); Anisotropy; Conduction electrons; Photoionization
Disciplines
Atomic, Molecular and Optical Physics | Nuclear | Physical Chemistry
Language
English
Permissions
Use Find in Your Library, contact the author, or use interlibrary loan to garner a copy of the article. Publisher copyright policy allows author to archive post-print (author’s final manuscript). When post-print is available or publisher policy changes, the article will be deposited.
Rights
IN COPYRIGHT. For more information about this rights statement, please visit http://rightsstatements.org/vocab/InC/1.0/
Repository Citation
Arce, J. C.,
Sheehy, J. A.,
Langhoff, P. W.,
Hemmers, O.,
Wang, H.,
Focke, P.,
Sellin, I. A.,
Lindle, D. W.
(2001).
On the Angular Distributions of Molecular Photoelectrons: Dipole Cross Sections for Fixed-in-Space and Randomly Oriented Molecules.
Chemical Physics Letters, 346
341-346.