A New Lithium-Rich Anti-Spinel in Li–O–Br System

Authors

Jianzhong Zhang, Los Alamos National LaboratoryFollow
Yusheng Zhao, University of Nevada, Las VegasFollow
L. Wang, University of Nevada, Las Vegas
J. Zhu, University of Nevada, Las Vegas

Document Type

Article

Publication Date

5-11-2015

Publication Title

Chemical Communications

Volume

51

Issue

47

First page number:

9666

Last page number:

9669

Abstract

In spinel-type materials currently known, the divalent anions are arranged in a closed-pack lattice and cations of various valences occupy some or all of the tetrahedral and octahedral sites. We report here the first discovery of an “electronically inverted” anti-spinel. The new material, crystallized in a defect spinel structure, was obtained from the dehydration of Li5Br(OH)4 under moderate pressure and temperature conditions.

Disciplines

Astrophysics and Astronomy

Repository Citation

Zhang, J., Zhao, Y., Wang, L., Zhu, J. (2015). A New Lithium-Rich Anti-Spinel in Li–O–Br System. Chemical Communications, 51(47), 9666-9669.
http://dx.doi.org/10.1039/C5CC01109D