"Photofragmentation of SO2 following Photoexcitation Near the Sulfur L2" by Wayne C. Stolte, Renaud Guillemin et al.
 

Photofragmentation of SO2 following Photoexcitation Near the Sulfur L2,3 Threshold

Document Type

Article

Publication Date

6-2005

Publication Title

Journal of Electron Spectroscopy and Related Phenomena

Volume

144-147

First page number:

157

Last page number:

160

Abstract

We report an extensive study on total and partial-ion-yield spectroscopy around the S 2p threshold in SO2. All positive and negative single-ion channels have been measured. Several cation fragments with the same mass/charge ratio could be distinguished by taking advantage of the 34S isotope. The O yield as a function of photon energy shows strong enhancement on the below-threshold resonances with two broad weak peaks above threshold corresponding to doubly excited resonances.

Keywords

Anions; Atomic orbitals; Core-level; Electron configuration; Fragmentation reactions; Photofragmentation; Sulfur dioxide

Disciplines

Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Physical Chemistry

Language

English

Permissions

Use Find in Your Library, contact the author, or use interlibrary loan to garner a copy of the article. Publisher copyright policy allows author to archive post-print (author’s final manuscript). When post-print is available or publisher policy changes, the article will be deposited

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