Document Type

Article

Publication Date

2010

Publication Title

Journal of Chemical Physics

Volume

133

Issue

014306

First page number:

014306-1

Last page number:

014306-6

Abstract

We have investigated the photofragmentation properties of the three-membered ring heterocyclic molecule ethylene sulfide or thiirane, C2H4S, by time-of-flight mass spectroscopy. Positive ions have been collected as a function of photon energy around the S K ionization threshold. Branching ratios were derived for all detected ions, which are informative of the decay dynamics and photofragmentation patterns of the core-excited species. We present a new assignment of the spectral features around the S K-edge.

Keywords

Atomic orbitals; Electron configuration; Mass spectroscopy; Organosulfur compounds

Disciplines

Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Physical Chemistry

Language

English

Permissions

Copyright American Institute of Physics, used with permission

Identifier

DOI: 10.1063/1.3457946

Publisher Citation

Stolte, Wayne C., and G. Öhrwall. "Sulfur K-edge photofragmentation of ethylene sulfide." The Journal of chemical physics 133 (2010): 014306.

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