Fragmentation of Methyl Chloride Studied by Partial Positive and Negative Ion Yield Spectroscopy

Authors

D. Ceolin, Uppsala UniversityFollow
Maria Novella Piancastelli, Uppsala UniversityFollow
Renaud Guillemin, CNRS, Laboratoire de Chimie Physique-Matière et RayonnementFollow
Wayne C. Stolte, University of Nevada, Las VegasFollow
S-W Yu, Lawrence Berkeley National LaboratoryFollow
Oliver Hemmers, University of Nevada, Las VegasFollow
Dennis W. Lindle, University of Nevada, Las VegasFollow

Document Type

Article

Publication Date

2-2007

Publication Title

Journal of chemical physics

Publisher

American Institute of Physics

Volume

126

Issue

8

First page number:

084309-1

Last page number:

084309-8

Abstract

The authors present partial-ion-yield experiments on the methyl chloride molecule excited in the vicinity of the Cl2p and C1s inner shells. A large number of fragments, cations produced by dissociation or recombination processes, as well as anionic species, have been detected. Although the spectra exhibit different intensity distributions depending on the core-excited atom, general observations include strong site-selective fragmentation along the C–Cl bond axis and a strong intensity dependence of transitions involving Rydberg series on fragment size.

Controlled Subject

Chemical bonds; Collisions (Nuclear physics); Ion recombination

Disciplines

Biological and Chemical Physics | Inorganic Chemistry | Nuclear | Physical Chemistry

File Format

pdf

File Size

854 KB

Language

English

Permissions

Copyright (2007) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.

Rights

IN COPYRIGHT. For more information about this rights statement, please visit http://rightsstatements.org/vocab/InC/1.0/

Repository Citation

Ceolin, D., Piancastelli, M. N., Guillemin, R., Stolte, W. C., Yu, S., Hemmers, O., Lindle, D. W. (2007). Fragmentation of Methyl Chloride Studied by Partial Positive and Negative Ion Yield Spectroscopy. Journal of chemical physics, 126(8), 084309-1-084309-8.
https://digitalscholarship.unlv.edu/hrc_fac_articles/12