Title

On the Angular Distributions of Molecular Photoelectrons: Dipole Cross Sections for Fixed-in-Space and Randomly Oriented Molecules

Document Type

Article

Publication Date

10-2001

Publication Title

Chemical Physics Letters

Publisher

Elsevier

Volume

346

First page number:

341

Last page number:

346

Abstract

New theoretical expressions are devised employing a dynamical perspective for photoionization cross-sections differential in electron ejection angles for both fixed-in-space and randomly oriented molecules, and comparisons made with K-shell ionization measurements in molecular nitrogen. Closed-form cross-sectional expressions are obtained in the dipole limit in terms of molecular body-frame transition moments and related normalized angular-distribution amplitudes which can be calculated employing interaction-prepared states without reference to specific scattering boundary conditions, and which reduce to more familiar atomic expressions in appropriate limits.

Keywords

Angular distribution (Nuclear physics); Anisotropy; Conduction electrons; Photoionization

Disciplines

Atomic, Molecular and Optical Physics | Nuclear | Physical Chemistry

Language

English

Permissions

Use Find in Your Library, contact the author, or use interlibrary loan to garner a copy of the article. Publisher copyright policy allows author to archive post-print (author’s final manuscript). When post-print is available or publisher policy changes, the article will be deposited.

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