On the Angular Distributions of Molecular Photoelectrons: Dipole Cross Sections for Fixed-in-Space and Randomly Oriented Molecules
Chemical Physics Letters
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New theoretical expressions are devised employing a dynamical perspective for photoionization cross-sections differential in electron ejection angles for both fixed-in-space and randomly oriented molecules, and comparisons made with K-shell ionization measurements in molecular nitrogen. Closed-form cross-sectional expressions are obtained in the dipole limit in terms of molecular body-frame transition moments and related normalized angular-distribution amplitudes which can be calculated employing interaction-prepared states without reference to specific scattering boundary conditions, and which reduce to more familiar atomic expressions in appropriate limits.
Angular distribution (Nuclear physics); Anisotropy; Conduction electrons; Photoionization
Atomic, Molecular and Optical Physics | Nuclear | Physical Chemistry
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Arce, J. C.,
Sheehy, J. A.,
Langhoff, P. W.,
Sellin, I. A.,
Lindle, D. W.
On the Angular Distributions of Molecular Photoelectrons: Dipole Cross Sections for Fixed-in-Space and Randomly Oriented Molecules.
Chemical Physics Letters, 346