Solution processed SiNxCyOz thin films thermally transformed from silicon oxide/melamine hybrid system
In this study, a solution-processable precursor of melamine and silicon oxide, was prepared and thermally converted into inorganic thin films of SiNxCyOz. Using tetra-ethoxysilane and hydroxyl-methyl-melamine, a transparent coating with a high loading content of silica of up to 50% was achieved through the hydrolysis/condensation reactions, which provided a transmittance of 85.1% (thickness of 1.5 ± 0.2 μm) and hard coating grade of 4H pencil test. When the silica/melamine coating was further heat-treated up to 900 °C in an inert environment, the organic melamine was converted into an inorganic compound composed of Si, N, C, and O atoms in the form of SiNxCyOz. The relative compositions of films varied with the heat-treatment temperature, e.g., providing SiN0.03C0.59O1.87 for the thin film heat-treated at 700 °C. The resulting inorganic thin films were mechanically strong and optically shiny with a low root mean square of roughness (< 1.0 nm) giving dielectric constants varying from 2.75 to 1.82 with heat treatment temperature that could be used as low-k materials in commercialized optoelectronic devices.
Coatings; Dielectrics; Electrooptical devices; Hardness; Low dielectric constant; Silicon-based thin films; Silicon oxide; Sol–gel reaction; Solution-processable; Thin films
Chemical Engineering | Materials Science and Engineering | Mechanical Engineering
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Cho, S. M.,
Kim, S. W.,
Nam, J. D.
Solution processed SiNxCyOz thin films thermally transformed from silicon oxide/melamine hybrid system.
Thin Solid Films, 539