Synthesis and Chemical Stability of Technetium Nitrides

Authors

Emily Siska, University of Nevada, Las VegasFollow
Dean Smith, University of Nevada, Las Vegas
Ashkan Salamat, University of Nevada, Las VegasFollow
Keith V. Lawler, University of Nevada, Las VegasFollow
Barbara Lavina, University of Nevada, Las Vegas
Frederic Poineau, University of Nevada, Las VegasFollow
Paul M. Forster, University of Nevada, Las VegasFollow

Document Type

Article

Publication Date

7-12-2021

Publication Title

Chemical Communications

Volume

57

Issue

65

First page number:

8079

Last page number:

8082

Abstract

We demonstrate the synthesis and phase stability of TcN, Tc2N, and a substoichiometric TcNx from 0 to 50 GPa and to 2500 K in a laser-heated diamond anvil cell. At least potential recoverability is demonstrated for each compound. TcN adopts a previously unpredicted structure identified via crystal structure prediction.

Disciplines

Biological and Chemical Physics | Physical Chemistry

Language

English

Repository Citation

Siska, E., Smith, D., Salamat, A., Lawler, K. V., Lavina, B., Poineau, F., Forster, P. M. (2021). Synthesis and Chemical Stability of Technetium Nitrides. Chemical Communications, 57(65), 8079-8082.
http://dx.doi.org/10.1039/D1CC02525B