Hydrothermal Synthesis and Solid-state Structures of Polynuclear Technetium Iodide Compounds

Authors

William M. Kerlin, University of Nevada Las Vegas, Las VegasFollow
Frederic Poineau, University of Nevada, Las VegasFollow
Paul M. Forster, University of Nevada, Las VegasFollow
Kenneth R. Czerwinski, University of Nevada Las Vegas, Las VegasFollow
Alfred P. Sattelberger, University of Nevada Las Vegas, Las VegasFollow

Document Type

Article

Publication Date

1-1-2015

Publication Title

Inorganica Chimica Acta

Volume

424

Issue

1

First page number:

329

Last page number:

335

Abstract

Two new technetium iodide compounds, Tc2(O2CCH3)4I and K[Tc8(μ-I)8I4]I, were synthesized in an autoclave from the reaction of KTcO4 in glacial acetic acid with hydroiodic acid and/or alkali metal iodide salts at 210 °C under 60–70 atm hydrogen pressure. The structures of Tc2(O2CCH3)4I and K[Tc8(μ-I)8I4]I were solved by single-crystal X-ray diffraction.

Keywords

Technetium compounds; Metal–metal interaction; Cluster compounds; Hydrothermal synthesis; Structure elucidation

Repository Citation

Kerlin, W. M., Poineau, F., Forster, P. M., Czerwinski, K. R., Sattelberger, A. P. (2015). Hydrothermal Synthesis and Solid-state Structures of Polynuclear Technetium Iodide Compounds. Inorganica Chimica Acta, 424(1), 329-335.
http://dx.doi.org/10.1016/j.ica.2014.09.024