Fragmentation Dynamics of H2S Following S 2p Photoexcitation

Authors

Renaud Guillemin, CNRS, Laboratoire de Chimie Physique-Matière et RayonnementFollow
S-W Yu, Lawrence Berkeley National LaboratoryFollow
Wayne C. Stolte, University of Nevada, Las VegasFollow
Dennis W. Lindle, University of Nevada, Las VegasFollow

Document Type

Article

Publication Date

2005

Publication Title

Journal of Chemical Physics

Volume

122

Issue

094318

First page number:

8

Abstract

The fragmentation dynamics of core-excited H₂S has been studied by means of partial anion and cation yield measurements around the S L_2,3-subshell ionization thresholds. All detectable ionic fragments are reported, and significant differences between partial ion yields are observed. Possible dissociation pathways are discussed by comparison to previous studies of electron spectra.

Keywords

Atomic orbitals; Electron configuration; Electronic excitation; Fragmentation reactions; Hydrogen sulfide; Ionization

Disciplines

Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Physical Chemistry

Language

English

Comments

DOI: 10.1063/1.1860012

Permissions

Copyright American Institute of Physics, used with permission

Repository Citation

Guillemin, R., Yu, S., Stolte, W. C., Lindle, D. W. (2005). Fragmentation Dynamics of H2S Following S 2p Photoexcitation. Journal of Chemical Physics, 122(094318), 8.
https://digitalscholarship.unlv.edu/chem_fac_articles/23