Document Type
Article
Publication Date
11-20-2018
Publication Title
Environments
Publisher
MDPI
Volume
5
Issue
11
First page number:
1
Last page number:
18
Abstract
A voltammetric method was used to estimate the complexing capacity of water extracts from both desert soils sampled at the root zone of creosote and salt cedar plants, and in soils from interspace or background regions where no vegetative influence was apparent. The copper complexing capacity of water extracts of these desert soils was influenced by contact time and pH. In soils from the root zones of creosote and salt cedar plant, copper complexation capacities at pH 8 were from 5 µM to 60 µM after five min contact periods, while 18 h contact periods yielded copper complexation capacities of 40 µM–80 µM. Soils with no vegetative influence had copper complexing capacities of less the 2 µM. The copper complexing capacities of these soils are well correlated with the concentration of organic carbon in the water extract (r2 = 0.86). The abundance of soluble organic matter in the root zone of desert shrubs has the potential to control the solution speciation of Cu2+. The formation of soluble complexes should also have an important influence on the plant uptake and transport of copper, as well as other heavy metals in the root zones of desert shrubs and beyond.
Keywords
Copper; Soluble organic matter; Humic substance; Creosote; Salt cedar
Disciplines
Bioresource and Agricultural Engineering
File Format
File Size
2.771 Kb
Language
English
Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.
Repository Citation
Steinberg, S. M.,
Hodge, V. F.
(2018).
Copper Complexation by Dissolved Organic Matter in arid Soils: A Voltametric Study.
Environments, 5(11),
1-18.
MDPI.
http://dx.doi.org/10.3390/environments5110125