Controlling the Stereodynamics of Cold Molecular Collisions

Document Type

Conference Proceeding

Publication Date

5-29-2019

Publication Title

Bulletin of the American Physical Society

Publisher

American Physical Society

Volume

64

Issue

4

Abstract

We report numerically-exact quantum scattering calculations for low-energy collisions of quantum-state prepared HD with H2. Excellent agreement is obtained with recent measurements of Perreault et al. for the angular distribution of scattered HD at a collision energy of 1 K. By state-preparation of the HD molecules, control of the angular distribution of scattered HD was demonstrated. The stereo-dynamic control is achieved by the ability to choose a single or a coherent superposition of quantum states. We present a first-principles simulation of the experiment which enables us to attribute the main features of the observed angular distribution to a single L = 2 partial-wave shape resonance.

Disciplines

Atomic, Molecular and Optical Physics | Physical Sciences and Mathematics | Physics

Language

English


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