Technetium Electrochemistry at the Turn of the Century

Authors

Vitaly V. Kuznetsov, A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Maciej Chotkowski, University of Warsaw
Frederic Poineau, University of Nevada, Las VegasFollow
Mikhail A. Volkov, A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Konstantin German, A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Elena A. Filatova, Mendeleev University of Chemical Technology of Russia

Document Type

Article

Publication Date

4-23-2021

Publication Title

Journal of Electroanalytical Chemistry

Volume

893

First page number:

1

Last page number:

7

Abstract

The review summarizes and discusses the fundamental and scientific advances on the electrochemistry of Tc over the past 3 decades. The review focuses on thermodynamics, speciation data and redox chemistry of Tc species in oxidation state + VII to + III in aqueous media and of low valent and polynuclear species in organic media. The electrochemical behavior of Tc metal and alloys is reviewed and potential electrochemical applications discussed. The review is dedicated to the memory of Alexander Glebovich Maslennikov, a technetium scientist of IPCE RAS.

Keywords

Alloys; Aqueous media; Electrochemistry; Low valent species; Metal; Nuclear fuel cycle; Organic media; Pertechnetate; Polynuclear species; Speciation; Technetium

Disciplines

Physical Chemistry

Language

English

Repository Citation

Kuznetsov, V., Chotkowski, M., Poineau, F., Volkov, M., German, K., Filatova, E. (2021). Technetium Electrochemistry at the Turn of the Century. Journal of Electroanalytical Chemistry, 893 1-7.
http://dx.doi.org/10.1016/j.jelechem.2021.115284