Document Type
Article
Publication Date
7-1997
Publication Title
Physical Review Letters
Volume
79
Issue
3
First page number:
383
Last page number:
386
Abstract
Experimental and theoretical studies are reported on the inelastic (Raman) scattering of wavelength-selected polarized x rays from the K edge of gas-phase chlorine molecules. The polarized emission spectra exhibit prominent nondipole features consequent of phase variations of the incident and emitted radiation over molecular dimensions, as predicted by the Kramers-Heisenberg scattering formalism. Issues pursuant to the detection of core-hole localization by resonant Raman scattering from homonuclear diatomic molecules are critically examined. [S0031-9007(97)03486-8]
Keywords
Chlorine; Diatomic molecules; Raman effect; Raman spectroscopy
Disciplines
Analytical Chemistry | Atomic, Molecular and Optical Physics | Biological and Chemical Physics | Elementary Particles and Fields and String Theory | Physical Chemistry
Language
English
Permissions
Copyright American Physical Society, used with permission
Repository Citation
Mills, J. D.,
Sheehy, J. A.,
Ferrett, T. A.,
Southworth, S. H.,
Mayer, R.,
Lindle, D. W.,
Langhoff, P. W.
(1997).
Nondipole Resonant X-ray-Raman Spectroscopy: Polarized Inelastic Scattering at the K Edge of Cl2.
Physical Review Letters, 79(3),
383-386.
https://digitalscholarship.unlv.edu/chem_fac_articles/65
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