CIGS Device Models with Variations of Buffer Layer, Alkali Content, and Oxidation

Document Type

Conference Proceeding

Publication Date

1-5-2020

Publication Title

2021 47th IEEE Virtual Photovoltaic Specialists Conference (PVSC)

First page number:

508

Last page number:

514

Abstract

Nine types of CIGS cells were studied with permutations of sodium content, buffer type (CdS or Zn(O, S)), and post-deposition treatment (PDT) with KF, RbF, or oxidation. JV, QE, and CV measurements are presented for several cells of each type. KF PDT with CdS buffer resulted in the highest efficiency. Although Zn(O, S) buffer cells with typical sodium content had relatively low efficiency, RbF PDT significantly improved performance. Oxidation alone significantly increased the efficiency of sodium deficient cells with CdS buffer. Numerical modeling was conducted to connect device properties to the observed performance variations.

Keywords

CIGS cells; Cd-free buffer; Device simulation; Alkali post-deposition treatment

Disciplines

Engineering | Mechanical Engineering | Other Mechanical Engineering

Language

English

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