"The origin of brucite in hydrothermally altered limestone near Devil P" by Rhonda Lee Knupp

The origin of brucite in hydrothermally altered limestone near Devil Peak, Nevada

Rhonda Lee Knupp, University of Nevada, Las Vegas

Abstract

Open-space brucite was identified in veins crosscutting hydrothermally altered limestone near the Devil Peak rhyolite plug in southern Nevada. The brucite occurs with serpentine, calcite, chalcedony, hydromagnesite, dolomite, and clinochlore; Brucite usually forms as a replacement mineral, but textural evidence indicates that the brucite at Devil Peak precipitated in open space. The presence of chalcedony in veins indicates the temperature of the hydrothermal fluid was {dollar}<{dollar}180{dollar}\sp\circ{dollar}C during and after mineral deposition. Thermodynamic modeling shows this temperature is too low for replacement brucite to form, thus the low temperature of alteration may be a factor in this unusual occurrence of brucite; Infiltration modeling of isotopically depleted wall rocks shows that the hydrothermal fluid was initially composed of a mixture of metamorphic and meteoric water, with X{dollar}\rm\sb{CO2}{dollar} = 0.15-0.16. Later, an influx of magmatic fluid or metamorphic water mixed with the early fluid. Fluid inclusion analysis shows {dollar}\rm X\sb{CO2} < 0.01{dollar} for the fluid mixture.