Award Date
1-1-1995
Degree Type
Thesis
Degree Name
Master of Science (MS)
Department
Physics
Number of Pages
58
Abstract
A space-focused ion time-of-flight mass spectrometer was used to study the relaxation dynamics of HCl, DCl, and H{dollar}\sb2{dollar}S following the excitation of a K-shell electron using synchrotron radiation. On resonance, fragmentation of the molecule involving neutral dissociation of hydrogen was found to be a significant decay channel, thus raising questions of how effectively dissociation competes with Auger decay in the relaxation process. In addition, a space-focused ion time-of-flight mass spectrometer was constructed to be optimized for use at the Advanced Light Source in Berkeley, California. Peaks with less than 1 ns full-width at half-maximum have been observed.
Keywords
Chloride; Deuterium; Energies; Flight; Focused; Hard; Hydrogen; Ion; Mass; Ray; Space; Spectrometer; Spectroscopy; Sulfide; Time
Controlled Subject
Molecular dynamics; Nuclear physics; Chemistry, Physical and theoretical
File Format
File Size
2252.8 KB
Degree Grantor
University of Nevada, Las Vegas
Language
English
Permissions
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Repository Citation
Hansen, David Linnemann, "A space focused ion time of flight mass spectrometer, and spectroscopy of hydrogen chloride, deuterium chloride, and hydrogen sulfide at "hard" x-ray energies" (1995). UNLV Retrospective Theses & Dissertations. 534.
http://dx.doi.org/10.25669/ai5u-nvb0
Rights
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